Deklarit constraints engine
While not an RDBMS altogether, Deklarit supplies SQL's deficiencies in constraints.
FirstSQL
Java in-memory SQL92 DBMS with sane NULLs processing. Purports to actually strive to follow Codd's rules.
rdb
Makers of a very simple quasi-relational database based on Unix shell commands.
System R
The first implementation corrupted from the relational model, was the basis for SQL and DB2. A site preserving early history of a technology that became a critical business tool.
Unity
Another Unix filter implementation of some relational ideas.
Versata rules engine
A rules engine allowing declarative rules to be automatically enforce, thus implementing the constraints aspect of an RDBMS.